Andrey Rogachev

  • Assistant Professor of Chemistry


Ph.D. Chemistry, Moscow State University

Professional Affiliations & Memberships

American Chemical Society

Royal Society of Chemistry

American Association for the Advancement of Science


  • *C. Farber, J. Li, E. Hager, R. Chemelewski, J. Mullet, A.Yu.Rogachev, D. Kurouski, “Complementarity of Raman and Infrared Spectroscopy for Structural Characterization of Plant Epicuticular Waxes” //*ACSOmega*,2019, *4*, 3700-3707. [ view online» ]

  • *A.Yu. Rogachev,Z. Zhou, S. Liu, Q.Xu, J. Li, S.N.Spisak, Z. Wei, M.A. Petrukhina, “Placing Metal in the Bowl: Does RimcAlkylation Matter?” // *Organometallics*, 2019, *38*, 552-566. [view online>>]

  • *H. Han, Z. Wei, A.S. Filatov, J.C. Carozza, M. Alkan, A.Yu.Rogachev, A. Shevtsov, A.M. Abakumov, C. Pak, M. Shatruk, Y.-S. Chen,E.V.Dikarev, “Three to Tango Requires Some Substitutional Flexibility: Hetertrimetallic Li-Mn-Co Molecular Precursor” // *Chem. Sci.*, 2019,*10*,524-534. [ view online» ]

  • *J. Li, D. Tadakamalla, A.Yu. Rogachev,“ModulatingStability of Functionalized Cations [R-C60]+ with the Nature of R-Group”// *J.Comput. Chem*., 2018, *39*, 2385-2396. [ view online» ]

  • *S. Liu, A.Yu. Rogachev, “Comprehensive TheoreticalStudy of Interactions between Ag+ and Polycyclic Aromatic Hydrocarbons” //*ChemPhysChem.*, 2018, *19*, 2579-2588. [ view online» ]

  • A.V. Zabula, S.N. Spisak, A.S. Filatov, A.Yu. Rogachev, M.A. Petrukhina, “Record Alkali Metal Intercalation by Highly-Charged Bowls” // Acc. Chem. Res., 2018, 51, 1541-1549. DOI:10.1021/acs.accounts.8b00141 [ view online » ]

  • H. Han, Z. Wei, M.C. Barry, J.C. Carozza, M. Alkan, A.Yu. Rogachev, A.S. Filatov, A.M. Abakumov, E.V. Dikarev, “Three body problem: genuine heterotrimetallic vs. a statistical mixture of two parent heterobimetallic molecules” // Chem. Sci., 2018, ASAP. DOI:10.1039/C8SC00917 [ view online » ]
    • Selected for Cover Page.
  • J.J. Hrudka, H. Phan, A.Yu. Rogachev, M. Shatruk, “The Power of Three: Incremental Increase in the Field Strength of N-Alkylated 2,2'-Biimidazoles Leads to Spin Crossover in Homoleptic Fe(II) Complexes” // Inorg. Chem., 2018, 57, 5183-5193. [ view online » ]
  • S.N. Spisak, A.V. Zabula, M. Alkan, A.S. Filatov, A.Yu. Rogachev, M.A. Petrukhina, “Site-Directed Dimerization of Bowl-Shaped Radicals to Form a s-Bonded Charged Dibenzocorannulene Dimer” // Angew. Chem., Int. Ed., 2018, 57, 6171-6175. [ view online » ]
  • Z. Zhou, Q. Xu, A.Yu. Rogachev, S.N. Spisak, Z. Wei, M. Marcaccio, M.A. Petrukhina, “Fusing Planar Group to a p-Bowl: Electronic and Molecular Structure, Aromaticity and Solid State Packing of Naphthocorannulene and its Anions” // Chem. Eur. J., 2018, 24, 2455-3463. [ view online » ]
    • Selected for Cover Page.
  • S.N. Spisak, J. Li, A.Yu. Rogachev, Z. Wei, T. Amaya, T. Hirao, M.A. Petrukhina, “Crown Ether-Assisted Convex Cesium Binding to Sumanenyl Bowl” // Organometallics, 2017, 36, 4961-4967. [ view online » ]
  • S. Shokri, J. Li, M.K. Manna, G. Wiederrecht, D.J. Gosztola, A. Ugrinov, S. Jockusch, A.Yu. Rogachev, A.J.-L. Ayitou “A Naphtho-p-quinodimethane Exhibiting Baird’s (Anti-)Aromaticity, Broken Symmetry and Attractive Photoluminescence” // J. Org. Chem., 2017, 82, 10167-10173. [ view online » ]
  • A.Yu. Rogachev, J. Li, M.A. Petrukhina “Exploring Energetics in Dirhodium Paddle-Wheel Complexes with p-Ligands of Different Topologies” // J. Organomet. Chem., 2017, 849-850, 22-30. ( invited article) [ view online » ]
  • C.M. Lieberman, M.C. Barry, Z. Wei, A.Yu. Rogachev, X. Wang, J.-L. Liu, R. Clérac, Y.-S. Chen, A.S. Filatov, E.V. Dikarev “Position Assignment and Oxidation State Recognition of Fe and Co Centers in Heterometallic Mixed-Valent Molecular Precursors for the Low-Temperature Preparation of Target Spinel Oxide Materials” // Inorg. Chem., 2017, 56, 9574-9584. [ view online » ]
  • Q. Xu, M.A. Petrukhina, A.Yu. Rogachev, “Stepwise Deprotonation of Sumanene: Electronic Structure, Energetics and Aromaticity Alterations” // Phys. Chem. Chem. Phys., 2017, 19, 21575-21583. [ view online » ]
  • S. N. Spisak, A.Yu. Rogachev, A. V. Zabula, A. S. Filatov, R. Cléracde, and M. A. Petrukhina, "Tuning the separation and coupling of corannulene trianion-radicals through sizable alkali metal belts," // Chem. Sci., 2017, 8, 3137-3145. [ view online » ]
  • S. N. Spisak, Z. Wei, A.Yu. Rogachev, T. Amaya, T. Hirao, and M. A. Petrukhina, "Double Concave Cesium Encapsulation by Two Charged Sumanenyl Bowls" // Angew. Chem., Int. Ed., 2017, 56, 2582-2587. [ view online » ]
    • Selected for Cover Page.
  • A.V. Zabula, I. Guzei, R. West, J. Li, A.Yu. Rogachev, “Thermal Oligomerization of N-Heterocyclic Silylene into Zwitter-Ionic Silenes” // Angew. Chem., Int. Ed., 2016, 55, 13465-13469. [ view online » ]
  • S. Spisak, J. Li, A.Yu. Rogachev, Z. Wei, O. Papaianina, K. Amsharov, A. Rybalchenko, A. Goryunkov, M. Petrukhina, “From Corannulene to Indacenopicene: Effect of Carbon Framework Topology on Aromaticity and Reduction Limits” // Organometallics, 2016, 35, 3105-3111. [ view online » ]
    • Selected for Cover Page.
  • J. Li, G. da Silva Ramos, A.Yu. Rogachev, “Stability of Functionalized Corannulene Cations [R-C20H10]+: An Influence of the Nature of R-Group” // J. Comput. Chem., 2016, 37, 2266-2278. [ view online » ]
    • Selected for Cover Page.
  • J. Li, A.Yu. Rogachev, “Aromatic Stabilization of Functionalized Corannulene Cations” // Phys. Chem. Chem. Phys., 2016, 18, 11781-11 (invited article).
  • A.V. Zabula, S.N. Spisak, A.S. Filatov, A.Yu. Rogachev, V.M. Grigoryants, M.A. Petrukhina “Supramolecular Trap for a Transient Corannulene Trianion” // Chem. Sci., 2016, 7, 1954-1961. [ view online » ]
  • Y. Chen, X. Sun, J. Li, Y. Zhong, S. Jin, Z. Liu, N. Wu, A.Yu. Rogachev, H.-S. Chong “Synthetic and Mechanistic Investigation on One-Pot Halogenation of b-Amino Alcohols and Nucleophilic Ring Opening of Aziridinium Ions” // Org. Biomolec. Chem., 2016, 14, 920-939.
  • S.N. Spisak, Z. Wei, N.J. O’Neil, A.Yu. Rogachev, T. Amaya, T. Hirao, M.A. Petrukhina “Convex and Concave Encapsulation of Multiple Potassium Ions by Sumanenyl Anions” // J. Am. Chem. Soc., 2015, 137, 9768-9771. [ view online » ]
    • Highlighted in Computational Chemistry Highlights: September Issue, 2015.
    • Highlighted in Computational Organic Chemistry: “Sumanene Anions,” September 2015
  • C. Dubceac, A.S. Filatov, A.V. Zabula, A.Yu. Rogachev, M.A. Petrukhina “Functionalized Corannulene Carbocations: A Structural Overview” // Chem. Eur. J., 2015, 21, 14268-14279. [ view online » ]
    • Selected for Cover page.
  • A.Yu. Rogachev, M.-S. Miao, G. Merino, R. Hoffmann “Molecular CsF5 and CsF2+” // Angew. Chem., Int. Ed., 2015, 54, 8275-8278. [ view online » ]
  • C.M. Lieberman, A.S. Filatov, Z. Wei, A.Yu. Rogachev, A.M. Abakumov, E.V. Dikarev “Mixed-Valent, Heteroleptic Homometallic Diketonates as Templates for the Design of Heterometallic Precursors” // Chem. Sci., 2015, 6, 2835-2845. [ view online » ]
  • A.S. Filatov, S.N. Spisak, A.V. Zabula, J. McNeely, A.Yu. Rogachev, M.P. Petrukhina “Dynamic Transformations of Self-Assembled Sandwich Products Formed by Tetrareduced Corannulene with Mixed Core Alkali Metal Clusters” // Chem. Sci., 2015, 6, 1959-1966. [ view online » ]
  • J. Li, A.Yu. Rogachev “SO2 – Yet Another Two-Faced Ligand” // Phys. Chem. Chem. Phys., 2015, 17, 1987-2000.
  • A.V. Zabula, A.Yu. Rogachev, R. West “Self-Assembly of N-Heterocyclic Derivatives of Divalent Germanium, Tin and Lead” // Chem. Eur. J., 2014, 20, 16652-16656. [ view online » ]
  • N. Sumner, S. Spisak, A. Zabula, A. Filatov, A. Rogachev, M. Petrukhina “Alkali Metal Intercalation in Curved Carbon Networks: X-Ray Structural Study” // Acta. Cryst., Sect. A, 2014, A70, C986.
  • N.S. Sumner, S.N. Spisak, A.S. Filatov, A.Yu. Rogachev, A.V. Zabula, M.A. Petrukhina “Double Concave Binding of Bicorannulenyl Dianion: Cesium vs. Lithium Salts” // Organometallics, 2014, 33, 2874-2878. [ view online » ]
  • A.S. Filatov, A.V. Zabula, S.N. Spisak, A.Yu. Rogachev, M.A. Petrukhina “Clamshell effect of highly charged corannulene decks for maximizing the intercalated content in the mixed metal supramolecular aggregates” // Angew. Chem., Int. Ed., 2014, 53, 140-145. [ view online » ]
    • Highlighted in Nature Chemistry: “Metals in the Middle”, Nature Chem., 2014, 6, 4.

Selected Publications Before Professor Rogachev Joined Illinois Institute of Technology

  • A.Yu. Rogachev, R. Hoffmann. Iodine (I2) as a Janus-Faced Ligand in Organometallics. J. Am. Chem. Soc., 2013, 135, 3262. [ view online » ]
  • A.Yu. Rogachev, X.-D. Wen, R. Hoffmann. Jail-Breaking Benzene Dimers. J. Am. Chem. Soc., 2012, 134, 8062. [ view online » ]
  • A.Yu. Rogachev, A.S. Filatov, A. Zabula, M. A. Petrukhina, Functionalized Corannulene Cations: Detailed Theoretical Survey. Phys. Chem. Chem. Phys., 2012, 14, 3554.
  • A.Yu. Rogachev, P. Burger. Bonding Situation and N–O-Bond Strength in Amine-N-Oxides—A Combined Experimental and Theoretical Study. Phys. Chem. Chem. Phys., 2012, 14, 1985.
  • A.V. Zabula, A.S. Filatov, S.N. Spisak, A.Yu. Rogachev, M.A. Petrukhina. A Main Group Metal Sandwich: Five Lithium Cations Jammed Between Two Corannulene Tetraanion Decks. Science, 2011, 333, 1008. [ view online » ]
  • S.N. Spisak, A.V. Zabula, A.S. Filatov, A.Yu. Rogachev, M.A. Petrukhina. Selective Endo and Exo Binding of Alkali Metals to Corannulene. Angew. Chem., Int. Ed., 2011, 50, 8090. [ view online » ]


Chemistry at magnetic centers, theoretical point of view; luminescence and bioluminescence; chemistry and physics of curved polyaromatic systems (buckybowls and fullerenes); multi-reference approach to spectroscopic, magnetic and catalytic properties of organic, organometallic and bio-(in)organic systems.

Andrey Rogachev

Contact Information

312.567.3151 312.567.3289 390 Robert A. Pritzker Science Center